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2KMnO₄ + 5Na₂C₂O₄ + 8H₂SO₄ ---> K₂SO₄ + 2MnSO₄ + 5Na₂SO₄ + 10CO₂ + 8H₂O
Mn(VII) + 5e ---> Mn(II) /*2
2C(III) ---> 2C(IV) + 2e /*5
mNa₂C₂O₄=134u
mKMnO₄=158u
2*158g KMnO₄ --- 5*134g Na₂C₂O₄
xg KMnO₄ --------- 0,2g Na₂C₂O₄
x = 0,094g KMnO₄
n=m/M
n=0,094/158
n = 0,000595mola
0,1mola ----- 1000cm³
0,000595mola ---- xcm³
x = 5,95cm³ KMnO₄