z góry dzięki:)
Zad.1.alkohol:V, aldehyd:III, ester:VI, kwasy:I
1a)
I. 2CH3-COOH + ZnO-->(CH3COO)2Zn + H2O
II.CH3-CH2-NH2 + HCl-->CH3-CH2-NH3[+]Cl[-]
V.CH2(OH)-CH2(OH) + 2Na-->CH2(ONa)-CH2(ONa) + H2
VI.CH3-CH2-COO-CH(CH3-CH3 + NaOH--> CH3-CH2-COO-Na + CH3CH(OH)CH3
1b)
2CH3-COOH + Zn --.(CH3-COO)2Zn + H2
1mol Zn=65g 1mol H2=22,4dm3
65g-------224dm3
12g-------x x=4,135dm2-tyle wodoru sie wydzieli
1c) a)to związek nr V, b)to zawiązek o nr.III
reakcja nr b)
CH3-CH2-CHO + 2Cu(OH)2---> CH3-CH2-COOH + Cu2O + 2H2O
1d)
III. CH3-CH2-CH2-OH + CuO--> CH3-CH2-CHO + Cu + H2O
IV.CH3-CH(OH)-CH3 + CuO--> CH3-CO-CH3 + Cu+ H2O
VI.CH3-CH2-COOH + CH3-CH(OH)-CH3 --> CH3-CH2-COOCH-(CH3)2
Zad.2
I-kwas octowy, III-propanal
Zad.3
będący kwasem: CH3-CH(CH3)-COOH - kwas 2-metylopropanowy
będocy estrem: 1)CH3-CH2-COOCH3 - propylan metylu,
2)CH3-COOCH2-CH3 - octan etylu
Zad.4
C3H5-(COO-C17H35)3 + 3NaOH--> C3H5(OH)3 + 3C17H35-COONa
Zad.5
alkohol II-rzędowy: CH3-CH(OH)-CH3 -propan-2-ol
amina II-rzędowa: C2H5-NH-CH3 - etylometyloamina
Zad.6
CH3-CH(OH) + CH3OH -->CH3-CH(OH)-COOCH3 + H2O
Zad.7
1.(CH3COO)2Ba + Na2SO4 --> BaSO4 + 2CH3-COONa
2.CH3OH + CH3-CH2-COOH--> CH3-CH2-COOCH3 + H2O
3.HCOOH + NaOH-->HCOONa + H2O
4.C2H5OH + Na-->CH3-CH2ONa + 1/2H2
5.CH3OH+ Ag2O-->HCOOH + 2Ag + H2O
Zad.8
2C17H35COONa + MgCl2--> (C17H35COO)2Mg + 2NaCl
2C17H35COO[-] + 2Na[+] + Mg[2+] + 2Cl[-]--> (C17H25COO)2Mg + 2Na[+] + 2Cl[-]
Zad.9
w probówce nr 2 nastąpiło odbarwienie
CH3-(CH2)7-CH=CH-(CH2)7-COOH + Br2--> CH3-(CH2)7-CHBr-CHBr-(CH2)7-COOH
Zad.10
papierek uniwersalny zabarwi sie na w 1)na zielono-niebieski
w 2)na czerwono
I. CH3-NH2 + H2O<==>CH3NH3[+] + OH[-]
II.C3H7COOH<==> C3H7COO[-] + H[+] - na strzałkach w tej reakcji napisz H2O
Zad.11
C17H31COOCH2-CH2-CH3 + KOH--> C17H 31COOK + CH2(OH)-CH2-CH3
Zad.12
1)CH3-CH2-CH3Cl + KOH-->CH3-CH2-CH2-OH + KCl - na strzałce w tej reakcji napisz H2O CH3-CH2-CH2-OH to związek X
2)CH3-CH2-CH2-OH + CuO-->CH3-CH2-CHO + Cu + H2O
CH3-CH2-CHO- to związek Y
3)CH3-CH2-CHO + 2Cu(OH)2-->CH3-CH2-COOH + Cu2O + H2O
CH3-CH2-COOH- to związek Z
4)CH3-CH2-COOH + CH3-CH2-OH-->CH3-CH2-COOCH2-CH3 + H2O
zad.1
alkohol:V
aldehyd:III
ester:IV
kwas:I
a) 2CH3COOH+ZnO->(CH3COO)2Zn+H2O
CH3Ch2NH2+HCl->CH3CH2Cl+NH3
CH2OH-CH2OH+2Na->CH2ONa-CH2ONa+H2
CH3CH2COOCH(CH3)CH3+NaOH->CH3CH2COONa+CH3CH(OH)CH3
b)2CH3COOH+Zn->(CH3COO)2Zn+H2
12g CH3COOH - X dm^3 H2
2*60g - 22,4 dm^3 H2
X=2,24 dm^3
c)A-v
B-III
CH3CH2CHO+Cu(OH)2->CH3CH2COOH+Cu2O+H2O
d)
CH3CH2CH2OH+CuO->CH3CH2CHO+Cu
C6H5CH(CH3)2+O2->C6H5OH+(CH3)2CO
CH3CH2COOH+CH3CH(OH)CH3->CH3CH2COOCH(CH3)CH3
zad.2
I-kwas octowy
III-propanal
zad.3
CH3CH2CH2CH2COOH kwas n-butanowy
CH3CH2COOCH2CH3 propanan etylu
CH3COOCH2CH2CH3 octan propylu
zad.4
(C17H35COO)3C3H5+3NaOH->3C17H35COONa+C3H5(OH)3
zad.5
II-rzędowy alkohol
CH3CH(OH)CH3 PROPAN-2-OL
II-rzędowa amina
CH3CH2(NH)CH2PROPYLOAMINA
zad.6
CH3CH(OH)COOH+CH3OH->>CH3CH(OH)COOCH3+H2O
zad.7
BaSO4+2CH3COONa
CH3CH2COOCH3+H2O
HCOONa+H2O
HCHO+Ag+H2O
zad.8
2C17H35COONa+MgCl2->(C17H35COO)2Mg+NaCl
zad.9
W 2
CH3(CH2)7CH=CH(CH2)7COOH+Br2->CH3(CH2)7(CHBr)2(CH2)7COOH
zad.10
metyloamina-zasadowy
kwas butanowy-słaby kwasowy
(w reakcji strzałki w obie strony)
CH3NH2+H2O->CH3OH+NH3
(nad strzałką H2O)
CH3CH2CH2CH2COOH->C4H9COO-+H+
zad.11
C15H31COOCH2CH3+KOH->C15H31COOK+CH3CH2CH2OH
zad.12
CH2ClCH2CH3+KOH->CH2OHCH2CH3+KCl
CH2OHCH2CH3+CuO->CH3CH2CHO+Cu+H2O
CH3CH2CHO+Cu(OH)2->CH3CH2COOH+Cu2O+2H2O
CH3CH2COOH+CH3CH2OH->CH3CH2COOCH2CH3+H2O
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Zad.1.alkohol:V, aldehyd:III, ester:VI, kwasy:I
1a)
I. 2CH3-COOH + ZnO-->(CH3COO)2Zn + H2O
II.CH3-CH2-NH2 + HCl-->CH3-CH2-NH3[+]Cl[-]
V.CH2(OH)-CH2(OH) + 2Na-->CH2(ONa)-CH2(ONa) + H2
VI.CH3-CH2-COO-CH(CH3-CH3 + NaOH--> CH3-CH2-COO-Na + CH3CH(OH)CH3
1b)
2CH3-COOH + Zn --.(CH3-COO)2Zn + H2
1mol Zn=65g 1mol H2=22,4dm3
65g-------224dm3
12g-------x x=4,135dm2-tyle wodoru sie wydzieli
1c) a)to związek nr V, b)to zawiązek o nr.III
reakcja nr b)
CH3-CH2-CHO + 2Cu(OH)2---> CH3-CH2-COOH + Cu2O + 2H2O
1d)
III. CH3-CH2-CH2-OH + CuO--> CH3-CH2-CHO + Cu + H2O
IV.CH3-CH(OH)-CH3 + CuO--> CH3-CO-CH3 + Cu+ H2O
VI.CH3-CH2-COOH + CH3-CH(OH)-CH3 --> CH3-CH2-COOCH-(CH3)2
Zad.2
I-kwas octowy, III-propanal
Zad.3
będący kwasem: CH3-CH(CH3)-COOH - kwas 2-metylopropanowy
będocy estrem: 1)CH3-CH2-COOCH3 - propylan metylu,
2)CH3-COOCH2-CH3 - octan etylu
Zad.4
C3H5-(COO-C17H35)3 + 3NaOH--> C3H5(OH)3 + 3C17H35-COONa
Zad.5
alkohol II-rzędowy: CH3-CH(OH)-CH3 -propan-2-ol
amina II-rzędowa: C2H5-NH-CH3 - etylometyloamina
Zad.6
CH3-CH(OH) + CH3OH -->CH3-CH(OH)-COOCH3 + H2O
Zad.7
1.(CH3COO)2Ba + Na2SO4 --> BaSO4 + 2CH3-COONa
2.CH3OH + CH3-CH2-COOH--> CH3-CH2-COOCH3 + H2O
3.HCOOH + NaOH-->HCOONa + H2O
4.C2H5OH + Na-->CH3-CH2ONa + 1/2H2
5.CH3OH+ Ag2O-->HCOOH + 2Ag + H2O
Zad.8
2C17H35COONa + MgCl2--> (C17H35COO)2Mg + 2NaCl
2C17H35COO[-] + 2Na[+] + Mg[2+] + 2Cl[-]--> (C17H25COO)2Mg + 2Na[+] + 2Cl[-]
Zad.9
w probówce nr 2 nastąpiło odbarwienie
CH3-(CH2)7-CH=CH-(CH2)7-COOH + Br2--> CH3-(CH2)7-CHBr-CHBr-(CH2)7-COOH
Zad.10
papierek uniwersalny zabarwi sie na w 1)na zielono-niebieski
w 2)na czerwono
I. CH3-NH2 + H2O<==>CH3NH3[+] + OH[-]
II.C3H7COOH<==> C3H7COO[-] + H[+] - na strzałkach w tej reakcji napisz H2O
Zad.11
C17H31COOCH2-CH2-CH3 + KOH--> C17H 31COOK + CH2(OH)-CH2-CH3
Zad.12
1)CH3-CH2-CH3Cl + KOH-->CH3-CH2-CH2-OH + KCl - na strzałce w tej reakcji napisz H2O CH3-CH2-CH2-OH to związek X
2)CH3-CH2-CH2-OH + CuO-->CH3-CH2-CHO + Cu + H2O
CH3-CH2-CHO- to związek Y
3)CH3-CH2-CHO + 2Cu(OH)2-->CH3-CH2-COOH + Cu2O + H2O
CH3-CH2-COOH- to związek Z
4)CH3-CH2-COOH + CH3-CH2-OH-->CH3-CH2-COOCH2-CH3 + H2O
zad.1
alkohol:V
aldehyd:III
ester:IV
kwas:I
a) 2CH3COOH+ZnO->(CH3COO)2Zn+H2O
CH3Ch2NH2+HCl->CH3CH2Cl+NH3
CH2OH-CH2OH+2Na->CH2ONa-CH2ONa+H2
CH3CH2COOCH(CH3)CH3+NaOH->CH3CH2COONa+CH3CH(OH)CH3
b)2CH3COOH+Zn->(CH3COO)2Zn+H2
12g CH3COOH - X dm^3 H2
2*60g - 22,4 dm^3 H2
X=2,24 dm^3
c)A-v
B-III
CH3CH2CHO+Cu(OH)2->CH3CH2COOH+Cu2O+H2O
d)
CH3CH2CH2OH+CuO->CH3CH2CHO+Cu
C6H5CH(CH3)2+O2->C6H5OH+(CH3)2CO
CH3CH2COOH+CH3CH(OH)CH3->CH3CH2COOCH(CH3)CH3
zad.2
I-kwas octowy
III-propanal
zad.3
CH3CH2CH2CH2COOH kwas n-butanowy
CH3CH2COOCH2CH3 propanan etylu
CH3COOCH2CH2CH3 octan propylu
zad.4
(C17H35COO)3C3H5+3NaOH->3C17H35COONa+C3H5(OH)3
zad.5
II-rzędowy alkohol
CH3CH(OH)CH3 PROPAN-2-OL
II-rzędowa amina
CH3CH2(NH)CH2PROPYLOAMINA
zad.6
CH3CH(OH)COOH+CH3OH->>CH3CH(OH)COOCH3+H2O
zad.7
BaSO4+2CH3COONa
CH3CH2COOCH3+H2O
HCOONa+H2O
HCHO+Ag+H2O
zad.8
2C17H35COONa+MgCl2->(C17H35COO)2Mg+NaCl
zad.9
W 2
CH3(CH2)7CH=CH(CH2)7COOH+Br2->CH3(CH2)7(CHBr)2(CH2)7COOH
zad.10
metyloamina-zasadowy
kwas butanowy-słaby kwasowy
(w reakcji strzałki w obie strony)
CH3NH2+H2O->CH3OH+NH3
(nad strzałką H2O)
CH3CH2CH2CH2COOH->C4H9COO-+H+
zad.11
C15H31COOCH2CH3+KOH->C15H31COOK+CH3CH2CH2OH
zad.12
CH2ClCH2CH3+KOH->CH2OHCH2CH3+KCl
CH2OHCH2CH3+CuO->CH3CH2CHO+Cu+H2O
CH3CH2CHO+Cu(OH)2->CH3CH2COOH+Cu2O+2H2O
CH3CH2COOH+CH3CH2OH->CH3CH2COOCH2CH3+H2O