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utleniacz K2Cr2O7
reduktor KI
K2Cr2O7 + KI + H2SO4 → K2SO4 + Cr2(SO4)3 + I2 + H2O
Cr2O7^2- + 14H^+ + 6e^- → 2Cr^3+ + 7H2O | ·1
2I^- → I2 + 2e^- | ·3
K2Cr2O7 + 6KI + 7H2SO4 → 4K2SO4 + Cr2(SO4)3 + 3I2 + 7H2O
2.
utleniacz -powinno być H2O2
reduktor CrCl3
CrCl3 + H2O2 + NaOH → Na2CrO4 + NaCl + H2O
Cr^3+ + 8OH^- → CrO4^2- + 4H2O + 3e^- | ·2
H2O2 + 2e^- → 2OH^- | ·3
2CrCl3 + 3H2O2 + 10NaOH → 2Na2CrO4 + 6NaCl + + 8H2O
proszę :)