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PH masing-masing larutan sebelum bercampurCH3COOH 0,1 M (Ka = 10–5)
CH3COOH ⇔ H+ + CH3COO–
[H+ ] = \sqrt{Ka x M}
[H+ ] = \sqrt{ 10^{-6} }
[H+ ] = 10^{-3} M
pH = - log [H+ ]
= - log 10-3
= 3
NaOH 0,1 M
NaOH → Na+ + OH–
[OH- ] = x · [OH]
= 1 · 0,1
= 0,1 M
pOH = - log [OH- ]
= - log 0,1
= - log 10-1
= 1
pH = 14 – pOH
= 14 – 1
= 13
pH setelah pencampuran
Reaksi CH3COOH + NaOH → CH3COONa + H2O
Mol mula-mula 20 mmol 10 mmol
Mol reaksi 10 mmol 10 mmol 10 mmol 10 mmol
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Mol sisa 10 mmol - 10 mmol 10 mmol
(dalam 200 ml larutan)
[CH3COONa] = \frac{mol CH3COONa}{volume} \\ =\frac{10}{200}
= 0,05M
[CH3COOH] = \frac{(mol CH3COOH)}{volume} \\ =\frac{10}{200}
= 0,05M
H+ = Ka. \frac{CH3COOH}{CH3COONa}
H+ = 10-5 \frac{0,05}{0,05}
H+ = 10^{-5}
pH = -log [H+]
= -log 10-5
= 5
Jadi, pH setelah pencampuran adalah 5