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CH3CH2OH+H2O⇒CH3COOH+4H(+)+4e(-) /*3
Cr2O7(2-)+14H(+)+6e(-)⇒2Cr(3+)+7H2O /*2
--------------------------(↓równania po wymnożeniu↓)----------
3CH3CH2OH+3H2O⇒3CH3COOH+12H(+)+12e(-)
2Cr2O7(2-)+28H(+)+12e(-)⇒4Cr(3+)+14H2O
(+)------------------------------------------------------------------------(+)
3CH3CH2OH+3H2O+2Cr2O7(2-)+28H(+)⇒3CH3COOH+12H(+)+4Cr(3+)+14H2O
↓------------------------------------------------------------------------↓
3CH3CH2OH+2Cr2O7(2-)+16H(+)⇒3CH3COOH+4Cr(3+)+11H2O
na podstawie tego równania dobieramy współczynniki stechiometryczne .(jest to równanie pomocnicze)