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mol H₂SO₄ = 50 x 0,2 = 10 mmol
Persamaan reaksi :
. . 2NH₄OH + H₂SO₄ → (NH₄)₂SO₄ + 2H₂O
a. . .50. . . . . . 10
r. . . 20. . . . . . 10
_____________________________________
s. . . 30. . . . . . –. . . . . . . 10
Karena yang tersisa basa lemah, maka akan terbentuk sistem larutan penyangga
Reaksi ionisasi garam
(NH₄)₂SO₄ ⇆ 2NH₄⁺ + SO₄²⁻
. . 10. . . . . . . . 20. . . . . .10
[OH⁻] = KB • mol NH₄OH / mol NH₄⁺
[OH⁻] = 10⁻⁶ • 30/20
[OH⁻] = 1,5 x 10⁻⁶
poH = -log [OH⁻]
pOH = -log [1,5 x 10⁻⁶]
pOH = 6 - log 1,5
pH = 14 - pOH
pH = 14 - (6 - log 1,5)
pH = 8 + log 1,5 ☜ Jawaban ✔
Ok?