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mol urea = massa / Mr = 15 gram / 60 = 0,25 mol
mol air = massa / Mr = 85 gram / 18 = 4,72 mol
X urea = mol urea / (mol urea + mol air)
X urea = 0,25 / (0,25 + 4,72)
X urea ≈ 0,05 (D)