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ΔH°f C₂H₂ = - 52 kJ/mol
ΔH°f CO₂ = - 394 kJ/mol
ΔH°f H₂O = - 242 kJ/mol
Dit :
ΔH°f pada 6,72 liter etuna?
Jawab :
Buat persamaan kimia
C₂ + H₂ ---> C₂H₂ ΔH = - 52 kJ
C + O₂ ---> CO₂ ΔH = - 394 kJ
H₂ + 1/2O₂ ---> H₂O ΔH = - 242 kJ
Samakan reasi tersebut dengan rekasi
2C₂H₂ + 5O₂ ---> 4CO₂ + 2H₂O
C₂ + H₂ ---> C₂H₂ ΔH = - 52 kJ (x2 dan di pindah ruaskan
C₂H₂ ---> C₂ + H₂ ΔH = + 104 kJ
C + O₂ ---> CO₂ ΔH = - 394 kJ (x4)
4C + 4O₂ ---> 4CO₂ ΔH = - 1.576 kJ
H₂ + 1/2O₂ ---> H₂O ΔH = - 242 kJ (x2)
2H₂ + O₂ ---> 2H₂O ΔH = - 484 kJ
Jadi :
C₂H₂ ---> C₂ + H₂ ΔH = + 104 kJ
4C + 4O₂ ---> 4CO₂ ΔH = - 1.576 kJ
2H₂ + O₂ ---> 2H₂O ΔH = - 484 kJ
_____________________________________ +
2C₂H₂ + 5O₂ ---> 4CO₂ + 2H₂O ΔH = 1956 kJ
ΔH°f pada 6,72 liter etuna (C₂H₂)
n = liter / 22.4
n = 6,72 / 22,4
n = 0,3 Mol
ΔH°f (C₂H₂) = 1956/0,3
= 6.250 kJ/mol