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mol HCL =25.0,1=2,5 mmol
OH=Kb.(NH4OH/HCL)=10^-5(5/2.5)=10^-5.2=2.10^-5
pOH=-log 2.10^-5=5-log 2
pH =14-pOH=14-(5-log 2)=9+log 2=9+0,3=9,3
⇒n HCl = 25 mL x 0,1 M = 2,5 mmol
⇒ reaksinya
NH₄OH + HCl ⇔ NH₄Cl + H₂O
Mula" 5 mmol 2,5 mmol
Bereaksi 2,5 mmol 2,5 mmol 2,5 mmol
Sisa 2,5 mmol ----- 2,5 mmol
⇒ dikarenakan basa lemah yang bersisa, digunakan rumus buffer
[OH⁻] = Kb x (n basa / n garam)
= 10⁻⁵ x ( 2,5 mmol / 2,5 mmol)
= 10⁻⁵
pOH = -log 10⁻⁵
= 5
pH = 14 - 5
= 9