1 standardowa entalpia spalania C6H6= -3286kJ/mol. Oblicz standardowa entalpie tworzenia tego związku gdy standardowe entalpie tworzenia CO2= -393,51kJ/mol i H2O= -285,83 kJ/mol
2 oblicz standardową entalpie tworzenia cyklopropanu z pierwiastków o standardowe entalpie tworzenia reakcji: C+O2=CO2 H=-393,771 kJ, H2+1/2O2=H2O H=-286,032 kJ, C3H6 +9/2O2=3CO2 +H2O H=-2092,773 kj
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ZAD1
C6H6 + 9O2 = 6CO2 + 6H2O H1=-3286KJ/mol
C + O2 = CO2 H2=-393,5KJ/mol
H2 + 1/2O2 = H2O H3=-285,83KJ/mol
6C + 3H2 = C6H6 H=?
C6H6 + O2 = CO2 + H2O
H1=H2+H3-H
-3286KJ/mol=6(-393,5KJ/mol)-6(285,83KJ/mol)-H
-3286=-4075.98-H
H=789,98KJ/mol
ZAD2
3C+3H2=C3H6 H=?
C+O2=CO2 H1=-393,771 kJ
H2+1/2O2=H2O H2=-286,032 kJ
C3H6 +9/2O2=3CO2 +3H2O H3=-2092,773 kj
H3=H1+H2-H
-2092,773 kj=3(-393,771 kJ)+3(-286,032 kJ) - H
-2092,773=-2039,409-H
H=53,364KJ