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pH = 9
pOH = 14 - pH = 14 - 9
pOH = 5
[OH⁻] = 10⁻⁵
[OH⁻] = Kb • mol sisa basa/mol garam
10⁻⁵ = 10⁻⁵ • mol sisa basa/mol garam
mol sisa basa/mol garam = 10⁻⁵/10⁻⁵
mol sisa basa/mol garam = 1
mol sisa basa = mol garam
misal mol sisa basa = mol garam = 1 mol
Persamaan reaksi :
NH₄OH + HCl → NH₄Cl + H₂O
a 2 mol 1 mol
r 1 mol 1 mol
___________________________
s 1 mol - 1 mol
Jadi, mol NH₄OH : mol HCl = 2 : 1
Karena konsentrasi kedua larutan sama, berarti perbandingan mol = perbandingan volume. sehingga volume NH₄OH : volume HCl = 2 : 1
Jadi, x : y adalah 2 : 1