W podanych równaniach reakcji dobierz współczynniki stechiometryczne na podstawie bilansu elektronowego
a)PbO2+HCl->PbCl2+Cl2+H2O
b)P+HNO3+H20->H3PO4+NO
c)Hl+H2SO4->L2+H20+H2S
D)H2SO3+CL2+H20->H2SO4+HCl
" Life is not a problem to be solved but a reality to be experienced! "
© Copyright 2013 - 2024 KUDO.TIPS - All rights reserved.
a)
PbO₂ + HCl ------> PbCl₂ + Cl₂ + H₂O
-----------------------------------------
Bilans:
PbO₂ + 4H⁺ + 2e⁻ ----------> Pb²⁺ + 2H₂O
2Cl⁻ --------> Cl₂ + 2e⁻
PbO₂ + 4H⁺ + 2Cl⁻ ----------> Pb²⁺ + 2H₂O + Cl₂
____________________________
PbO₂ + 4HCl ------> PbCl₂ + Cl₂ + 2H₂O
b)
P + HNO₃ + H₂O -------> H₃PO₄ + NO
-------------------------------------------
Bilans:
P + 4H₂O --------> PO₄³⁻ + 8H⁺ + 5e⁻ |·3
NO₃⁻ + 4H⁺ + 3e⁻ ----------> NO + 2H₂O |·5
3P + 12H₂O + 5NO₃⁻ + 20H⁺-----> 3PO₄³⁻ + 24H⁺ + 5NO + 10H₂O
3P + 2H₂O + 5NO₃⁻-----> 3PO₄³⁻ + 4H⁺ + 5NO
___________________________________
3P + 5HNO₃ + 2H₂O -------> 3H₃PO₄ + 5NO
c)
HJ + H₂SO₄ ------> J₂ + H₂O + H₂S
---------------------------------------
Bilans:
SO₄²⁻ + 8H⁺ + 8e⁻ ----------> S²⁻ + 4H₂O
2J⁻ ---------> J₂ + 2e⁻ |·4
SO₄²⁻ + 8H⁺ + 8J⁻ -------> S²⁻ + 4H₂O + 4J₂
___________________________________
8HJ + H₂SO₄ ------> 4J₂ + 4H₂O + H₂S
d)
H₂SO₃ + Cl₂ + H₂O -----> H₂SO₄ + HCl
------------------------------------------
Bilans:
SO₃²⁻ H₂O---------> SO₄²⁻ + 2H⁺ + 2e⁻
Cl₂ + 2e⁻ ------> 2Cl⁻
SO₃²⁻ H₂O + Cl₂ ---------> SO₄²⁻ + 2H⁺ + 2Cl⁻
____________________________________
H₂SO₃ + Cl₂ + H₂O -----> H₂SO₄ + 2HCl