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H2SO4 (Asam Sulfat)
V = 100 mL
M = 0,2 M
Ba(OH)2 (Barium Hidroksida(
V = 100 mL
M = 0,4 mL
ditanya :
pH campuran = ....?
massa garam (BaSO4) = ...?
n H2SO4 = M × V
= 0,2 M × 100 mL
= 20 mmol
n Ba(OH)2 = M × V
= 0,4 M × 100 mL
= 40 mmol
H2SO4 + Ba(OH)2 => BaSO4 + 2 H2O
Pereaksi Pembatas =>H2SO4 karena jumlah mol nya lebih sedikit
n Ba(OH)2 sisa = n Ba(OH)2 awal - n H2SO4
= 40 mmol - 20 mmol
= 20 mmol
V total = 200 mL
[Ba(OH)2] sisa = n / V
= 20 mmol / 200 mL
= 0,1 M
[OH-] = b × [Ba(OH)] sisa
= 2 × 0,1
= 0,2
pOH = - log [OH-]
= - log (0,2)
= 1 - log 2
pH = pKw - pOH
= 14 - (1 - log 2)
= 13 + log 2
n BaSO4 = 20 mmol
(Hasil Reaksi dari Ba(OH)2 dan H2SO4)
Mr BaSO4 = 233
massa BaSO4 = n × Mr
= 20 mmol × 233
= 4660 mg
= 4,66 gram