Sebanyak 50 mL larutan NH3 0,1 M dicampur dengan 50 mL larutan HCl 0,1 M. Tentukan pH larutan sebelum dan sesudah dicampurkan. (Kb NH3 = 1 x 10-5). Tolong sama caranya :)
Amaldoft
A. pH sebelum dicampurkan 1. pH HCl [H+] = M x valensi = 0,1 x 1 = 10^-1 ---------------> pH = 1 2. pH NH3 [OH-] = √Kb x M = √10^-5 x 0,1 = 10^-3 ------------------------------> pH = 11
B. pH setelah dicampurkan *n NH3 = 50 mL x 0,1 M = 5 mmol *n HCl = 50 mL x 0,1 M = 5 mmol NH3 + HCl ---> NH4Cl m 5 5 b -5 -5 +5 s - - 5
*[NH4Cl] = ][NH4+] = 5 mmol / 50 mL + 50 mL = 0,05 Molar *[H+] = √Kw x [NH4+] / Kb = √10^-14 x 0,05 / 10^-5 = √5 x 10^-11 = 10^-5,5 x √5
1. pH HCl
[H+] = M x valensi
= 0,1 x 1
= 10^-1 ---------------> pH = 1
2. pH NH3
[OH-] = √Kb x M
= √10^-5 x 0,1
= 10^-3 ------------------------------> pH = 11
B. pH setelah dicampurkan
*n NH3 = 50 mL x 0,1 M = 5 mmol
*n HCl = 50 mL x 0,1 M = 5 mmol
NH3 + HCl ---> NH4Cl
m 5 5
b -5 -5 +5
s - - 5
*[NH4Cl] = ][NH4+] = 5 mmol / 50 mL + 50 mL = 0,05 Molar
*[H+] = √Kw x [NH4+] / Kb
= √10^-14 x 0,05 / 10^-5
= √5 x 10^-11
= 10^-5,5 x √5
pH = 5,5 - log √5