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pH NaOH = 12 + log 4
pOH NaOH = 2 - log 4
[OH⁻] = 4 x 10⁻²
M NaOH = 0,04
mol NaOH = 0,04 x 50
mol NaOH = 2 mmol
* Mencari Ka HCN
pH HCN = 6 - log 2
[H⁺] = 2 x 10⁻⁶
[H⁺] = √Ka . M
2 x 10⁻⁶ = √Ka . 0,01
4 x 10⁻¹² = Ka . 0,01
Ka = 4 x 10⁻¹⁰
* Mencari mol HCN
mol HCN = M x Volume
mol HCN = 0,01 x 200
mol HCN = 2 mmol
* Mencari Molaritas garan (NaCN)
Persamaan reaksi :
NaOH + HCN → NaCN + H₂O
Karena mol asam lemah (HCN) = mol basa kuat (NaOH), maka terbentuk sistem hidrolisis garam.
mol NaCN (garam) yang terbentuk = 2 mmol
M NaCN = mol/Volume total
M NaCN = 2/(200+50) = 2/250
M NaCN = 0,008 M
* Mencari [OH⁻]
[OH⁻] = √Kw/Ka • M garam
[OH⁻] = √10⁻¹⁴/4 x 10⁻¹⁰ • 0,008
[OH⁻] = √2 x 10⁻⁷
[OH⁻] = 4,47 x 10⁻⁴
* Mencari pOH
pOH = -log [OH⁻]
pOH = -log [4,47 x 10⁻⁴]
pOH = 4 - log 4,47
* Mencari pH
pH = 14 - pOH
pH = 14 - (4 - log 4,47)
pH = 10 + log 4,47
Jadi, pH larutan adalah 10 + log 4,47