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40mmol 5mmol
5mmol 5mmol 5mmol _
35mmol 5mmol
H=Ka*n CH3COOH/n CH3COOBa
H=10⁻⁵*35/5 =7*10⁻5
pH=-log7*10⁻⁵
pH=5-log7
mol Ba(OH)₂ = 50 x 0,1 = 5 mmol
Persamaan reaksi :
2CH₃COOH + Ba(OH)₂ → Ba(CH₃COO)₂ + 2H₂O
a 40 5
r 10 5
____________________________________________
s 30 mmol - 5 mmol
Terkjadi sistem Larutan Penyangga
Ba(CH₃COO)₂ ⇆ Ba²⁺ + 2CH₃COO⁻
5 5 10 mmol
mol sisa asam = 30 mmol
mol anion garam = 10 mmol
[H⁺] = Ka • mol sisa asam/mol anion garam
[H⁺] = 10⁻⁵ • 30/10
[H⁺] = 3 x 10⁻⁵
pH = -log [H⁺]
pH = -log [3 x 10⁻⁵]
pH = 5 - log 3
Jadi, pH campuran yang terjadi adalah 5 - log 3