Ke dalam 50 ml NaOH 0,1 M ditambahkan 50 ml HCOOH 0,1 M. Jika Ka asam formiat pada suhu 20 derajat sebeaar 1,8 x 10^-4, berapakah pH larutan garam yang terbentuk?
tolonggg ya, soalnya harus dikumpul skarang.
patriaprastikamol NaOH = 50 x 0,1 = 5 mmol mol HCOOH = 50 x 0,1 = 5 mmol
Persamaan reaksi : NaOH + HCOOH → HCOONa + H₂O a 5 5 r 5 5 ___________________________________ s - - 5 mmol
mol HCOONa = 5 mmol mol HCOO⁻ = 5 mmol
Molaritas HCOO⁻ = mol/Volume campuran M HCOO⁻ = 5/100 M HCOO⁻ = 0,05 M
[OH⁻] = √Kw/Ka • M anion garam [OH⁻] = √10⁻¹⁴/1,8 x 10⁻⁴ • 0,05 [OH⁻] = √2,77 x 10⁻¹² [OH⁻] = 1,66 x 10⁻⁶
mol HCOOH = 50 x 0,1 = 5 mmol
Persamaan reaksi :
NaOH + HCOOH → HCOONa + H₂O
a 5 5
r 5 5
___________________________________
s - - 5 mmol
mol HCOONa = 5 mmol
mol HCOO⁻ = 5 mmol
Molaritas HCOO⁻ = mol/Volume campuran
M HCOO⁻ = 5/100
M HCOO⁻ = 0,05 M
[OH⁻] = √Kw/Ka • M anion garam
[OH⁻] = √10⁻¹⁴/1,8 x 10⁻⁴ • 0,05
[OH⁻] = √2,77 x 10⁻¹²
[OH⁻] = 1,66 x 10⁻⁶
pOH = -log [OH⁻]
pOH = -log [1,66 x 10⁻⁶]
pOH = 6 - log 1,66
pH = 14 - pOH
pH = 14 - (6 - log 1,66)
pH = 8 + log 1,66
Jadi, pH larutan yang terbentuk adalah 8 + log 1,66