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Kb NH₃=2.10⁻⁵
M (NH₄)₂SO₄=9.10⁻³M
Dit: PH=?
Dij:
Berati hidrolisis garam ya.
(NH₄)₂SO₄ ⇆ 2NH₄⁺ + SO₄²⁻
0,009 0,018 M 0,009 M
M NH₄⁺ = 0,018 M
Garam (NH₄)₂SO₄ terbentuk dari NH₃ (basa lemah) dan H₂SO₄ (asam kuat). Sehingg, garamnya bersifat asam
[H⁺] = √Kw/Kb • M kation garam
= √10⁻¹⁴/2 x 10⁻⁵ • 0,018
= √1,8 x 10⁻¹⁶/2 x 10⁻⁵
= √9 x 10⁻¹²
= 3 x 10⁻⁶
pH = -log [H⁺]
= -log [3 x 10⁻⁶]
= 6 - log 3
= 6 - 0,47
= 5,53
Jadi, pH larutan garam (NH₄)₂SO₄ 0,0009 M adalah 5,53