Hitung pH campuran yang terdiri atas 50 mL larutan NH4OH 0,2 M dan 50 mL larutan HCl 0,2 M (Kb = 10^-5)!
safirainbow
Mol reaksi = 10 mmol, 10^-2 mol volume campuran = 50 ml + 50 ml = 100 ml = 10^-1
[H+] = √(kw/kb) x Mg x Val [H+]= √(10^-14/10^-5 ) x (10^-2/10^-1) [h+]= √10^-9 x 10^-1 [H+]= 10^-5 ph = -log [H+] ph = - log 10^-5 ph = 5
13 votes Thanks 12
Amaldoft
Diket dan dit: *n NH4OH = 50 mL x 0,2 M = 10 mmol *n HCl = 50 mL x 0,2 M = 10 mmol *Kb = 10^-5 *pH ?
NH4OH + HCl --> NH4Cl + H2O m 10 10 b -10 -10 +10 s - - 10
Bersisa garam, sehingga memakai rumus hidrolisis. Karena jumlah mol NH4Cl sama dengan jumlah mol NH4+ (spesi yang bisa di hidrolisis), maka: [NH4+]tot = 10 mmol/ 50 mL + 50 mL = 0,1 M [H+] = √Kw x [NH4+] / Kb = √10^-14 x 0,1 / 10^-5 = 10^-5 pH = 5
volume campuran = 50 ml + 50 ml = 100 ml = 10^-1
[H+] = √(kw/kb) x Mg x Val
[H+]= √(10^-14/10^-5 ) x (10^-2/10^-1)
[h+]= √10^-9 x 10^-1
[H+]= 10^-5
ph = -log [H+]
ph = - log 10^-5
ph = 5
*n NH4OH = 50 mL x 0,2 M = 10 mmol
*n HCl = 50 mL x 0,2 M = 10 mmol
*Kb = 10^-5
*pH ?
NH4OH + HCl --> NH4Cl + H2O
m 10 10
b -10 -10 +10
s - - 10
Bersisa garam, sehingga memakai rumus hidrolisis. Karena jumlah mol NH4Cl sama dengan jumlah mol NH4+ (spesi yang bisa di hidrolisis), maka:
[NH4+]tot = 10 mmol/ 50 mL + 50 mL
= 0,1 M
[H+] = √Kw x [NH4+] / Kb
= √10^-14 x 0,1 / 10^-5
= 10^-5
pH = 5