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Wt = 270 gram (Mr = 180 gram/mol)wp = 9 L = 9000 gram (Mr = 18 gram/mol)
a. P° = 30 mmHg
ΔP = .......................?
nt = wt/Mr = 270/180 = 1,5 mol
np = wp/Mr = 9000/18 = 500 mol
Xt = nt/(nt+np) = 1,5/(1,5+500) = 1,5/501,5 = 0,015
Xp = 1 - Xt = 1 - 0,015 = 0,985
ΔP = Xt.P°
= 0,015 x 30
= 0,45 mmHg
b. Kb = 1,86°C
ΔTb = ...................?
ΔTb = m.Kb
ΔTb = wt/Mr x 1000/wp x Kb
= 270/180 x 1000/9000 x 1,86
= 1,5 x 0,1 x 1,86
= 0,15 x 1,86
= 0,279°C
c. Kd = 0,52
ΔTd = ...................?
ΔTd = m.Kd
= 0,15 x 0,52
= 0,078°C