1. Ke dalam 300 mL larutan CH3COOH 0,1 M dicampurkan 50 mL larutan NaOH 0,2M. (Ka CH3COOH = ), pH larutan akan berubah dari : a. 3 menjadi 13 - log2 b. 1 menjadi 5 c. 3 menjadi 5 - log 2 d. 1 menjadi 13 - log 2 e. 3 menjadi 14
2. Jika Kb = , maka perbandingan volume kedua larutan tersebut adalah .... a. 1 : 1 b. 1 : 2 c. 2 : 1 d. 3 : 2 e. 3 : 4
Tolong bantu dengan caranya ya, terima kasih.. :) !!
Amaldoft
1. Jawaban: C. 3 menjadi 5 - log 2 *n CH3COOH = 300 mL x 0,1 = 30 mmol *n NaOH = 50 mL x 0,2 M = 10 mmol *Ka CH3COOH = 10^-5 *pH awal dan akhir?
A. pH awal [H+] = √Ka x [CH3COOH] = √10^-5 x 0,1 = 10^-3 -------------------> pH = 3
B. pH akhir CH3COOH + NaOH --> CH3COONa + H2O m 30 10 b -10 -10 +10 s 20 - 10
[H+] = Ka x [CH3COOH] / [CH3COONa] = 10^-5 x 20/10 = 2 x 10^-5 ----------------> pH = 5 - log 2
2. Jawaban: C. 2 : 1 *[H+] [OH-] = 10^-14 2 x 10^-5 x [OH-] = 10^-14 [OH-] = 5 x 10^-10
Misal, n CH3COOH = 0,1 M x V mL = 0,1Va n NaOH = 0,2M x V mL = 0,2Vb
CH3COOH + NaOH ---> CH3COONa + H2O m 0,1Va 0,2Vb b -0,2Vb -0,2Vb +0,2Vb s 0,1Va-0,2Vb - 0,2Vb
[OH-] = Kb x n CH3COOH / n CH3COONa 5 x 10^-10 = 10^-5 x (0,1Va-0,2Vb) / 0,2Vb 10^-5Vb = 0,1Va - 0,2Vb 0,20001Vb = 0,1Va 0,2Vb = 0,1Va Va/Vb = 0,2/0,1 Va : Vb = 2 : 1
NurulAriantiAR
10^-5Vb
yang dari 10^-5Vb = 0,1Va - 0,2Vb
itu dapat dari mana ya??
Amaldoft
Dari 10^-5 letakkan di bawah 5 x 10^-10 sehingga artinya 5 x 10^-10 : 10^-5, jadi 5 x 10^-5 = (0,1Va - 0,2Vb) / 0,2Vb. Nah, kali silang 5 x 10^-5 x 0,2Vb jadinya 10^-5Vb = 0,1Va - 0,2 Vb
NurulAriantiAR
Ooww, iy, iy, sy mengerti..
Terima kasih.. :) !!
*n CH3COOH = 300 mL x 0,1 = 30 mmol
*n NaOH = 50 mL x 0,2 M = 10 mmol
*Ka CH3COOH = 10^-5
*pH awal dan akhir?
A. pH awal
[H+] = √Ka x [CH3COOH]
= √10^-5 x 0,1
= 10^-3 -------------------> pH = 3
B. pH akhir
CH3COOH + NaOH --> CH3COONa + H2O
m 30 10
b -10 -10 +10
s 20 - 10
[H+] = Ka x [CH3COOH] / [CH3COONa]
= 10^-5 x 20/10
= 2 x 10^-5 ----------------> pH = 5 - log 2
2. Jawaban: C. 2 : 1
*[H+] [OH-] = 10^-14
2 x 10^-5 x [OH-] = 10^-14
[OH-] = 5 x 10^-10
Misal, n CH3COOH = 0,1 M x V mL = 0,1Va
n NaOH = 0,2M x V mL = 0,2Vb
CH3COOH + NaOH ---> CH3COONa + H2O
m 0,1Va 0,2Vb
b -0,2Vb -0,2Vb +0,2Vb
s 0,1Va-0,2Vb - 0,2Vb
[OH-] = Kb x n CH3COOH / n CH3COONa
5 x 10^-10 = 10^-5 x (0,1Va-0,2Vb) / 0,2Vb
10^-5Vb = 0,1Va - 0,2Vb
0,20001Vb = 0,1Va
0,2Vb = 0,1Va
Va/Vb = 0,2/0,1
Va : Vb = 2 : 1